Dr.Mario:
Successfully complete the game in classic mode as Mario.
Alternately, play 100 versus mode matches. The winner of the 100th match will fight Dr. Mario. Defeat him and he will become a playable character.
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Falco:
Complete the 100 man melee.
Alternately, play 300 versus mode matches.
Alternately, play in adventure mode and defeat Fox in under 30 seconds. Watch the intermission sequence to determine if you will fight him next. If Fox talks, then get ready to fight Falco. You can do this under any difficulty setting with any amount of stock (lives).
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Ganondorf:
Complete event mode #29 (Triforce Gathering)
Alternately, play 600 versus mode matches.
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Jigglypuff:
Complete the game with any character under any difficulty setting. Continues are allowed.
Alternately, fight 50 multi-player battles.
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Luigi:
Complete the first stage of adventure mode with a time of 3:32:99 to 3:32:00. You will have to battle Luigi and defeat him in under one minute. Finish the remainder of adventure mode. At the end of adventure mode you will fight Luigi. Defeat Luigi and he will become a playable character.
Alternately, finish the first stage of adventure mode with a time ending in 2 seconds. Example: 1:32:24
Alternately, playing 800 versus mode battles. After you have played 800 battles, the winner of the battle will be challenged by Luigi. Defeat him and he will become a playable character. If you lose, Luigi will challenge the winner of the next versus mode battle.
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Mewtwo:
In versus mode, play 700 battles or get a total of 20 hours of game play.
Alternately, play 20 hours in melee vs. mode
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Mr. Game & Watch:
Complete the target test mode with all of the other 24 characters.
Alternately, play over 1,000 versus mode matches.
Alternately, unlock all the stages, then complete the game all the other 24 characters.
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Pichu:
Complete event mode #37.
Complete adventure mode as Mewtwo.
Play 200 matches in versus mode.
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Marth:
Play with all 14 default characters in classic mode without continuing.
Alternately, play vs. mode more than 400 times.
Alternately, play versus mode with all of the default characters. Marth will challenge the last character you played as (if you won the match). If you lose against him, then he will reappear to challenge the winner of the next versus match.
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Roy:
Complete the game as Prince Marth in classic mode.
Alternately, play over 900 versus mode matches.
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Young Link:
Finish classic mode 10 times with different characters each time. One time must be with Link.
Alternately, complete adventure mode as Ganondorf.
Alternately, play 500 versus mode matches.
Alternately, defeat Master Hand with 03:33 as a time.
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